KINETICS OF ELECTRON-TRANSFER MEDIATED OXIDATIONS OF METHYL BENZENES BY RUTHENIUM(III) TRIS-BIPYRIDINE

被引：7
|
作者：
REED, RA
MURRAY, RW
机构：
[1] Kenan Laboratories of Chemistry, University of North Carolina, Chapel Hill
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1990年 / 285卷 / 1-2期
基金：
美国国家科学基金会;
关键词：
Cyclic Voltammetry - Electron Transfer - Methyl Benzene;
D O I：
10.1016/0022-0728(90)87117-3
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Methyl substituted benzenes can be electrocatalytically oxidized in acetonitrile solvent by electrogenerated [Ru(bpy)3]3+ in the presence of an electroinactive base, tosylate, or radical scavenger, styrene. The kinetics of the step in which the methyl benzene is oxidized to a radical cation by the metal complex are measured by rotated disk electrode voltammetry, for the faster reactions, and by controlled potential electrolysis, for the slowest reactions. The reaction rates vary systematically with the free energy. © 1990.
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页码：149 / 162
页数：14
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