BIS(2,4,6-TRI-TERT-BUTYLPHENYL)STANNANEDIYL - A DIARYLSTANNYLENE WITHOUT DONOR STABILIZATION

被引：99

作者：

WEIDENBRUCH, M

SCHLAEFKE, J

SCHAFER, A

PETERS, K

VONSCHNERING, HG

MARSMANN, H

机构：

[1] MAX PLANCK INST FESTKORPERFORSCH,W-7000 STUTTGART,GERMANY

[2] UNIV GESAMTHSCH PADERBORN,FACHBEREICH CHEM,W-4790 PADERBORN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 18期

关键词：

D O I：

10.1002/anie.199418461

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first diarylstannylene monomeric in the solid state and not stabilized by donor ligands is 1. The dark red compound forms in good yields from Sn[N(SiMe3)2]2 and RLi (R = 2,4,6‐tBu3C6H2). In solution 1 apparently isomerizes to give the sterically less encumbered stannylene RR′Sn: (R′  CH2C(Me)2 −3,5‐tBu2C6H3). (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1846 / 1848

页数：3

共 50 条

[1] BIS(2,4,6-TRI-TERT-BUTYLPHENYL)BICYCLOTETRAPHOSPHANE
RIEDEL, R
HAUSEN, HD
FLUCK, E
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (12): : 1056 - 1057
[2] 2,4,6-TRI-TERT-BUTYLPHENYL RADICAL
BARCLAY, LRC
GRILLER, D
INGOLD, KU
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (09) : 3011 - 3012
[3] P-(2,4,6-TRI-TERT-BUTYLPHENYL)AMINO-P'-(2,4,6-TRI-TERT-BUTYLPHENYL)DIPHOSPHENE
RUBAN, AV
ROMANENKO, VD
REITEL, GV
MARKOVSKII, LN
ZHURNAL OBSHCHEI KHIMII, 1989, 59 (12): : 2781 - 2782
[4] ON THE CHEMISTRY OF (2,4,6-TRI-TERT-BUTYLPHENYL)ISOCYANIDE
PAKUSCH, J
RUCHARDT, C
CHEMISCHE BERICHTE, 1989, 122 (08) : 1593 - 1594
[5] REACTIONS AND KINETICS OF (2,4,6-TRI-TERT-BUTYLPHENYL)PHENYLCARBENE
HIRAI, K
KOMATSU, K
TOMIOKA, H
CHEMISTRY LETTERS, 1994, (03) : 503 - 506
[6] 2-(2,4,6-TRI-TERT-BUTYLPHENYL)-1-PHOSPHAETHIN, 1,4-BIS-(TRIMETHYLSILOXY)-1,4-BIS-(2,4,6-TRI-TERT-BUTYLPHENYL)-2,3-DIPHOSPHABUTADIEN
MARKL, G
SEJPKA, H
TETRAHEDRON LETTERS, 1986, 27 (02) : 171 - 174
[7] Preparation of 2,4-bis(2,4,6-tri-tert-butylphenyl)-1,3-diphosphacyclobutenes from 2-(2,4,6-tri-tert-butylphenyl)-1-phosphaethyne and alkyllithiums
Ito, S
Sugiyama, H
Yoshifuji, M
CHEMICAL COMMUNICATIONS, 2002, (16) : 1744 - 1745
[8] ABINITIO CALCULATION OF BOAT BENZENES IN BIS(2,4,6-TRI-TERT-BUTYLPHENYL)PHOSPHINIC CHLORIDE
YOSHIFUJI, M
SHIMA, I
INAMOTO, N
AOYAMA, T
TETRAHEDRON LETTERS, 1981, 22 (32) : 3057 - 3060
[9] A NEW ROUTE TO BIS(2,4,6-TRI-TERT-BUTYLPHENYL)DIPHOSPHENE VIA SILYLATED COMPOUND
BERTRAND, G
COURET, C
ESCUDIE, J
MAJID, S
MAJORAL, JP
TETRAHEDRON LETTERS, 1982, 23 (35) : 3567 - 3570
[10] SYNTHESIS AND STRUCTURE OF BIS(2,4,6-TRI-TERT-BUTYLPHENYL)DIPHOSPHENE - ISOLATION OF A TRUE PHOSPHOBENZENE
YOSHIFUJI, M
SHIMA, I
INAMOTO, N
HIROTSU, K
HIGUCHI, T
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (15) : 4587 - 4589

← 1 2 3 4 5 →