STUDIES ON ORGANOLANTHANIDE COMPLEXES .37. REACTION OF DICYCLOPENTADIENYLYTTRIUM CHLORIDE WITH ACYL CHLORIDES IN TETRAHYDROFURAN - ACYLATIVE CLEAVAGE OF THE CP-Y PI-BOND AND TETRAHYDROFURAN RING

被引：28

作者：

QIAN, CT

QIU, AE

HUANG, YZ

CHEN, WJ

机构：

[1] Laboratory of Organometallic Chemistry, Shanghai Institute of Orgnic Chemistry, Academia Sinica, Shanghai, 200032

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 412卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/0022-328X(91)86041-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dicyclopentadienylyttrium chloride reacts with aromatic and aliphatic acid chlorides in tetrahydrofuran at room temperature, resulting in cleavage of the Cp-Y pi-bond to produce 1,5-diacylcyclopentadienes, and the acylative ring-opening of tetrahydrofuran. A possible reaction mechanism is proposed.

引用

页码：53 / 59

页数：7