TRIS(PENTAFLUOROPHENYL)GOLD(III) COMPLEXES WITH O-DONOR, N-DONOR OR S-DONOR LIGANDS

被引：43
|
作者：
USON, R
LAGUNA, A
LAGUNA, M
JIMENEZ, J
DURANA, ME
机构：
[1] Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-C.S.I.C.
来源：
INORGANICA CHIMICA ACTA | 1990年 / 168卷 / 01期
关键词：
D O I：
10.1016/S0020-1693(00)88021-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Au(C6F5)3(OEt2) is a better intermediate complex than Au(C6F5)3·tht (tht = tetrahydrothiophen). The former compound can be prepared from (NBu4) [Au(C6F5)3Br] and AgClO4 in diethylether and the ether ligand can be easily displaced by neutral ligands [L = THF, OCMe2, diox, EtOH, SPPh3, SPPh2Me, OPPh3, OAsPh3, NCMe, NCPh, NCPr, NCCHCH2, o(NC)2C6H4] as well as cationic ones [(X)PPh2CH2 PPh2R]+ [X = S, R = Me, CH2C6F5, COOMe, CH2Ph; X = O, R = CH2Ph] to give the corresponding neutral or cationic tris(pentafluorophenyl)gold(III) complexes most of which were hitherto unaccessible. © 1990.
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页码：89 / 92
页数：4
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