Catalytic Hydrodeoxygenation of Fatty Acids for Biodiesel Production

被引：10

作者：

Stepacheva, Antonina A. ^{[1
]}

Sapunov, Valentin N. ^{[2
]}

Sulman, Esther M. ^{[1
]}

Nikoshvili, Linda Zh. ^{[1
]}

Sulman, Mikhail G. ^{[1
]}

Sidorov, Alexander I. ^{[1
]}

Demidenko, Galina N. ^{[1
]}

Matveeva, Valentina G. ^{[1
]}

机构：

[1] Tver Tech Univ, Dept Biotechnol & Chem, A Nikitina Str 22, Tver 170026, Russia

[2] D Mendeleyev Univ Chem Technol Russia, Miusskaya Sq 9, Moscow 125047, Russia

来源：

BULLETIN OF CHEMICAL REACTION ENGINEERING AND CATALYSIS | 2016年 / 11卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

Fatty Acids; Catalytic Hydrodeoxygenation; Palladium Catalyst; Biodiesel;

D O I：

10.9767/bcrec.11.2.538.125-132

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

This paper is devoted to the production of second generation biodiesel via catalytic hydrodeoxygenation of fatty acids. Pd/C catalysts with different metal loading were used. The palladium catalysts were characterized using low-temperature nitrogen physisorption and X-ray photoelectron spectroscopy. It was revealed that the most active and selective catalyst was 1%-Pd/C which allowed reaching up 97.5% of selectivity (regarding to n-heptadecane) at 100% conversion of substrate. Moreover, the chosen catalyst is more preferable according to lower metal content that leads the decrease of the process cost. The analysis of the catalysts showed that 1%-Pd/C had the highest specific surface area compared with 5%-Pd/C. Copyright (C) 2016 BCREC GROUP. All rights reserved

引用

页码：125 / 132

页数：8

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