Excess molar volume and excess viscosity of benzyl alcohol plus 4-hydroxy-4-methyl-2-pentanone and water plus 4-hydroxy-4-methyl-2-pentanone binary systems at 298.15 K

被引:3
|
作者
DeDoz, MBG [1 ]
Solimo, HN [1 ]
机构
[1] UNIV NACL TUCUMAN, INST FIS, FAC CIENCIAS EXACTAS & TECNOL, RA-4000 SAN MIGUEL DE TUCUMAN, TUCUMAN, ARGENTINA
关键词
benzyl alcohol + diacetone alcohol; water + diacetone alcohol; binary systems; excess molar volume; excess viscosity;
D O I
10.1080/00319109508028412
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Densities, viscosities and refractive indices have been measured at 298.15 K for water + 4-hydroxy-4-methyl-2-pentanone and benzyl alcohol + 4-hydroxy-4-methyl-2-pentanone binary mixtures over the whole concentration range. From experimental densities and viscosities, excess molar volumes and excess viscosities, respectively have been calculated. These results are fitted with a Redlich-Kister polynomial relation and their coefficients were estimated. The experimental and calculate excess quantities are used to discuss the mixing behaviour of the components.
引用
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页码:79 / 86
页数:8
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