N-(2,3-Dimethylphenyl)-2-nitrobenzene-sulfonamide

被引:2
|
作者
Chaithanya, U. [1 ]
Foro, Sabine [2 ]
Gowda, B. Thimme [1 ]
机构
[1] Mangalore Univ, Dept Chem, Mangalagangothri 574199, Karnataka, India
[2] Tech Univ Darmstadt, Inst Mat Sci, D-64287 Darmstadt, Germany
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词
data-to-parameter ratio = 15.3; mean ̄(C-C) = 0.006 Å; R factor = 0.062; single-crystal X-ray study; T = 293 K; wR factor = 0.164;
D O I
10.1107/S1600536812042845
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
There are two independent molecules in the asymmetric unit of the title compound, C14H14N2O4S. The N-H bonds are syn to the ortho-nitro groups in the sulfonyl benzene rings and anti to the methyl groups in the aniline benzene rings. The molecules are twisted at the S-N bonds with torsion angles of -60.4 (3) and 58.8 (3)degrees in the two molecules. The dihedral angles between the planes of the sulfonyl and the anilino benzene rings are 53.67 ( 8) and 56.99 (9)degrees. The amide H atoms of both molecules are involved in an intramolecular hydrogen bond, generating an S(7) motif. In the crystal, pairs of N-H center dot center dot center dot O(S) hydrogen bonds link like molecules into inversion dimers.
引用
收藏
页码:O3188 / +
页数:11
相关论文
共 50 条
  • [1] N-(2,5-Dimethylphenyl)-2-nitrobenzene-sulfonamide
    Chaithanya, U.
    Foro, Sabine
    Gowda, B. Thimme
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O3426 - +
  • [2] N-(3,5-Dimethylphenyl)-2-nitrobenzene-sulfonamide
    Chaithanya, U.
    Foro, Sabine
    Gowda, B. Thimme
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2823 - +
  • [3] N-(2,3-Dimethylphenyl)succinimide
    Saraswathi, B. S.
    Gowda, B. Thimme
    Foro, Sabine
    Fuess, Hartmut
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O919 - U3047
  • [4] N-(2,3-dimethylphenyl)methanesulfonamide
    Gowda, B. Thimme
    Foro, Sabine
    Fuess, Hartmut
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O3014 - U3264
  • [5] N-(2,3-Dimethylphenyl)acetamide
    Gowda, B. Thimme
    Foro, Sabine
    Terao, Hiromitsu
    Fuess, Hartmut
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O964 - U1515
  • [6] N-(2,3-Dimethylphenyl)benzenesulfonamide
    Gowda, B. Thimme
    Foro, Sabine
    Babitha, K. S.
    Fuess, Hartmut
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O366 - U2545
  • [7] N-(2-Methylphenyl)-2-nitrobenzene-sulfonamide
    Chaithanya, U.
    Foro, Sabine
    Gowda, B. Thimme
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2649 - +
  • [8] N-(2,3-Dimethylphenyl)benzamide
    Gowda, B. Thimme
    Tokarcik, Miroslav
    Kozisek, Jozef
    Sowmya, B. P.
    Fuess, Hartmut
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O965 - U1527
  • [9] N-(2-Chlorophenyl)-2-nitrobenzene-sulfonamide
    Chaithanya, U.
    Foro, Sabine
    Gowda, B. Thimme
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : 02575 - +
  • [10] N-(2,3-Dimethylphenyl)-2-methylbenzamide
    Rodrigues, Vinola Z.
    Gowda, B. Thimme
    Sivy, Julius
    Vrabel, Viktor
    Kozisek, Jozef
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2011, 67 : O3496 - U780