DELOCALIZATION LENGTH AND STRUCTURE OF OLIGOPYRROLES AND OF POLYPYRROLE FROM THEIR VIBRATIONAL-SPECTRA

被引：48

作者：

ZERBI, G

VERONELLI, M

MARTINA, S

SCHLUTER, AD

WEGNER, G

机构：

[1] IBM CORP,ALMADEN RES CTR,SAN JOSE,CA 95120

[2] FREE UNIV BERLIN,INST ORGAN CHEM,W-1000 BERLIN 33,GERMANY

[3] MAX PLANCK INST POLYMER RES,W-6500 MAINZ,GERMANY

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 02期

关键词：

D O I：

10.1063/1.466580

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Oligopyrroles with increasing chain length and polypyrroles were recently synthesized with new chemical methods. In this paper, we analyze their infrared and Raman spectra. The spectra can be nicely interpreted in terms of recent theoretical concepts of vibrational dynamics of polyconjugated systems. The spectra thus become a tool for deriving information on the structure of these materials.

引用

页码：978 / 984

页数：7

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