SYNTHESIS, STRUCTURE, REACTIVITY, AND SOLUTION BEHAVIOR OF BIS(DICARBONYL[HYDRIDOTRIS(1,2,4-TRIAZOLYL)BORATO]RUTHENIUM(I))(RU-RU)

被引：24
|
作者：
SHIU, KB [1 ]
GUO, WN [1 ]
PENG, SM [1 ]
CHENG, MC [1 ]
机构：
[1] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 10764,TAIWAN
来源：
INORGANIC CHEMISTRY | 1994年 / 33卷 / 13期
关键词：
D O I：
10.1021/ic00091a048
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The concurrent short Ru-Ru and Ru-L bond lengths (L = axial ligand) and the stronger oxidation resistance found in [Ru{eta3-HB(tz)3}(CO)2]2 (1) (tz = 1,2,4-triazolyl) relatively to [Ru{eta3-HB(pz)3}(CO)2]2 (2) (pz = 1-pyrazolyl) lead to the recognition that the HOMO is probably a sigma orbital for 1 and 2, though both compounds have the same filled orbitals of sigma, pi, delta, delta* and pi* as [Ru2(CO)4(O2CMe)2L2].
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页码：3010 / 3013
页数：4
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