CONVENIENT RADICAL ALPHA-MONOALLYLATIONS OF CARBONYL-COMPOUNDS

被引：10

作者：

WATANABE, Y ^{[1
]}

YONEDA, T ^{[1
]}

OKUMURA, T ^{[1
]}

UENO, Y ^{[1
]}

TORU, T ^{[1
]}

机构：

[1] NAGOYA INST TECHNOL, DEPT APPL CHEM, SHOWA KU, NAGOYA, AICHI 466, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 10期

关键词：

D O I：

10.1246/bcsj.66.3030

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Free radical allylations of alpha-seleno carbonyl compounds with tributyl-substituted 2,4-pentadienyltin, 2-methyl-2-propenyltin, 2-butenyltin, and 3-methyl-2-butenyltin, are described. Such successful C-C bond formations, in particular with the 2-butenyltin and the 3-methyl-2-butenyltin, are owing to the high reactivity of the alpha-carbon radical, generated from a-seleno carbonyl compounds, toward allylic tin compounds.

引用

页码：3030 / 3033

页数：4

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