ELECTROCHEMICAL GENERATION OF REACTIVE NITROGEN SPECIES .14. ANODIC-OXIDATION OF N-ACYL-N',N'-DIMETHYLHYDRAZINES

被引:2
|
作者
FUCHIGAMI, T
SATO, T
NONAKA, T
机构
[1] Department of Electronic Chemistry, Tokyo Institute of Technology, Midori-Ku, Yokohama, 227
关键词
D O I
10.1016/0022-0728(90)87182-J
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The anodic behavior of N-acyl-N', N'-dimethylhydrazines was studied. Cyclic voltammograms of these hydrazines showed two anodic peaks and the second peak corresponded to the oxidation of the corresponding N, N,-coupling products. Macro-scale electrolysis at the first peak potential provided the N,N-coupling products, tetrazanes in reasonable yields. © 1990.
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页码:141 / 145
页数:5
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