PYROLYSIS OF METALLOCENE COMPLEXES (ETA-C5H4R)2MR2' - AN ORGANOMETALLIC ROUTE TO METAL CARBIDE (MC) MATERIALS (M = TI, ZR, HF)

被引：31

作者：

LANG, H ^{[1
]}

SEYFERTH, D ^{[1
]}

机构：

[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 1990年 / 4卷 / 06期

关键词：

PYROLYSIS; CERAMIC; METALLOCENE; TITANIUM; ZIRCONIUM; HAFNIUM; LOW TEMPERATURE ROUTE;

D O I：

10.1002/aoc.590040604

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The following compounds were prepared and their pyrolysis in a stream of argon was studied: (eta-5-C5H5)2Ti(C = CC6H5)2, (eta-5-C5H4SiMe3)2Ti(SH)2, [(eta-5-C5H5)Ti(mu-CH2)]2, (eta-5-C5H5)2ZrR2(R = CH2, CH2C6H5, N(CH3)2), (eta-5-C5H4CH3)2Zr(C = CC6H5)2, [(eta-5-C5H4SiMe3)2Zr(mu-S)]2, [(eta-5-C5H4SiMe3)2Hf(mu-S)]2 and (eta-5-C5H4SiMe3)2Hf(C = CC6H5)2. The products of bulk pyrolysis of these materials were formed in 20-40% yield, based on the charged sample weight, and consisted mainly of titanium carbide together with small amounts of amorphous carbon.

引用

页码：599 / 606

页数：8

共 50 条

[1] CHEMISTRY OF ORTHO-XYLIDINE METAL-COMPLEXES .2. PREPARATION AND PROPERTIES OF THE ORTHO-XYLIDINE, METAL(IV) COMPLEXES - [M(CH2C6H4CH2-O) (ETA-C5H4R)2] (M = TI, ZR, HF, OR NB, R = H OR SIME3) AND [(M'(CH2C6H4CH2-O)2(OC4H8))N] (M' = TI, ZR, OR HF) - X-RAY CRYSTAL-STRUCTURES OF THE METALLAINDANES [M(CH2C6H4CH2-O)-(ETA-C5H4R)2] (R = H, M = TI, ZR, OR HF, R = SIME3, M = NB)CH
BRISTOW, GS
LAPPERT, MF
MARTIN, TR
ATWOOD, JL
HUNTER, WF
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (03): : 399 - 413
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ATWOOD, JL
BARKER, GK
HOLTON, J
HUNTER, WE
LAPPERT, MF
PEARCE, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (20) : 6645 - 6652
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GAUTHERON, B
TAINTURIER, G
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JEFFERY, J
LAPPERT, MF
RILEY, PI
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ERKER, G
MUHLENBERND, T
NOLTE, R
PETERSEN, JL
TAINTURIER, G
GAUTHERON, B
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 314 (1-2) : C21 - C24
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PICKETT, CJ
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YARROW, PIW
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GILSON, DFR
FITZPATRICK, PJ
GOMEZ, G
BUTLER, IS
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