REACTIONS OF THE AQUAPENTACYANOFERRATE(II) ION WITH 2-NITROSO-1-NAPHTHOL AND 2-NITROSO-1-NAPHTHOL-4-SULFONIC ACID

被引：24
|
作者：
FORETIC, B [1 ]
BURGER, N [1 ]
HANKONYI, V [1 ]
机构：
[1] UNIV ZAGREB,FAC MED,DEPT CHEM & BIOCHEM,ZAGREB 41000,CROATIA
来源：
POLYHEDRON | 1995年 / 14卷 / 05期
关键词：
D O I：
10.1016/0277-5387(94)00280-R
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The aqua ligand of the aquapentacyanoferrate(II) ion was replaced by 2-nitroso-1-naphthol and its sulphonate derivative giving the analogous mononuclear nitrosonaphtholpentacyanoferrate(II) complex in the first stage of the reaction. In the second stage, a cyano-bridged binuclear product was obtained and characterized as pentacyanoferrate(II)-mu-cyano-tricyanonitrosonaphtholferrate(II). The latter reaction was catalysed by mercury(II) ions. The complexes were characterized on the basis of analytical, IR and W-vis spectral data and have in the solid state and in solution a predominately quinone oximic structure. The preparation of the tris(2-nitroso-1-naphthol) ferrate(II) complex is also reported.
引用
收藏
页码：605 / 609
页数：5
相关论文
共 50 条
12345