ACYLATED CYANIDIN 3-RUTINOSIDE-5,3'-DIGLUCOSIDE FROM THE PURPLE-RED FLOWER OF LOBELIA ERINUS

被引：15
|
作者：
SAITO, N
TOKI, K
KUWANO, H
MORIYAMA, H
SHIGIHARA, A
HONDA, T
机构：
[1] MEIJI GAKUIN UNIV,CHEM LAB,YOKOHAMA,KANAGAWA 224,JAPAN
[2] MINAMI KYUSHU UNIV,FLORICULTURE LAB,MIYAZAKI 884,JAPAN
[3] HOSHI UNIV,INST MED CHEM,TOKYO 142,JAPAN
[4] INST SCI & TECHNOL INC,TOKYO 140,JAPAN
来源：
PHYTOCHEMISTRY | 1995年 / 39卷 / 02期
关键词：
LOBELIA ERINUS; LOBELIACEAE; FLOWER COLOR; ACYLATED ANTHOCYANIN; CYANIDIN; 3-RUTINOSIDE-3'; 5-DIGLUCOSIDE; P-COUMARIC; CAFFEIC; MALONIC ACIDS; INTRAMOLECULAR STACKING STRUCTURE;
D O I：
10.1016/0031-9422(94)00876-U
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A new acylated anthocyanin was isolated from the purple-red flowers of Lobelia erinus cv 'Rosamond'. Its structure was elucidated to be cyanidin 3-O-(6-0-(4-O-trans-p-coumaryl-alpha-L-rhamnopyranosyl) -beta-D-glucopyranoside)-5-O-(6-O-malonyl-beta-D-glucopyranoside)-3'-O(6-O-trans-caffeyl-beta-D-glucopyranoside) by spectroscopic evidence. The three dimensional structure of this pigment was suggested from the observation of difference negative NOE spectrum analysis that cyanidin (chromophore) and caffeic acid (intracopigment) occupy a folding conformation as a stacking structure.
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收藏
页码：423 / 426
页数：4
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