OBSERVATION OF THE LOW-ENERGY EXTERNAL VIBRATIONS OF BENZENE ON RH(111)

被引：23
|
作者：
WITTE, G
RANGE, H
TOENNIES, JP
WOLL, C
机构：
[1] UNIV HEIDELBERG,INST ANGEW PHYS CHEM,NEUENHEIMER FELD 253,D-69120 HEIDELBERG,GERMANY
[2] MAX PLANCK INST STROMUNGSFORSCH,D-37073 GOTTINGEN,GERMANY
来源：
PHYSICAL REVIEW LETTERS | 1993年 / 71卷 / 07期
关键词：
D O I：
10.1103/PhysRevLett.71.1063
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
The low frequency vibrations of benzene molecules adsorbed on Rh(111) have been investigated with inelastic He atom scattering. Well resolved energy losses of 13.1, 12.9, and 12.7 meV were observed for the pure benzene (2 square-root 3 x 3) structure, the CO + C6H6 c(2 square-root 3 x 4)rect and (3 x 3) structures, respectively. As these are the first experimental data for vibrations of a large adsorbed molecule in this energy regime extended Hueckel calculations were used to identify the observed mode as the frustrated translation of the benzene molecule parallel to the surface.
引用
收藏
页码：1063 / 1066
页数：4
相关论文
共 50 条
  • [1] Low-energy dynamics of CO and NO chemisorbed on Rh(111)
    Witte, G
    JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (06): : 2757 - 2767
  • [2] LOW-ENERGY VIBRATIONS OF INDENE
    CAMINATI, W
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (23): : 4153 - 4155
  • [3] INTERACTIONS OF UV PHOTONS AND LOW-ENERGY ELECTRONS WITH CHEMISORBED BENZENE ON AG(111)
    ZHOU, XL
    CASTRO, ME
    WHITE, JM
    SURFACE SCIENCE, 1990, 238 (1-3) : 215 - 225
  • [4] Low-temperature observation of the softened C-H stretching vibrations of cyclohexane on Rh(111)
    Koitaya, Takanori
    Beniya, Atsushi
    Mukai, Kozo
    Yoshimoto, Shinya
    Yoshinobu, Jun
    PHYSICAL REVIEW B, 2009, 80 (19)
  • [5] COADSORPTION STRUCTURES OF BENZENE AND CARBON-MONOXIDE ON RH(111) AND PT(111) BY HIGH-RESOLUTION ELECTRON-ENERGY LOSS SPECTROSCOPY AND LOW-ENERGY ELECTRON-DIFFRACTION
    VANHOVE, MA
    LIN, RF
    OGLETREE, DF
    BLACKMAN, GS
    MATE, CM
    SOMORJAI, GA
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1987, 5 (04): : 692 - 693
  • [6] Low-energy vibrations in superionic glasses
    Bartolotta, A
    Carini, G
    D'Angelo, G
    Tripodo, G
    SOLID STATE IONICS, 1998, 105 (1-4) : 97 - 102
  • [7] LOW-ENERGY ISOVECTOR QUADRUPOLE VIBRATIONS
    FAESSLER, A
    NOJAROV, R
    PHYSICS LETTERS B, 1986, 166 (04) : 367 - 371
  • [8] IS BENZENE DISTORTED ON RH(111)
    MCCABE, T
    LLOYD, DR
    SURFACE SCIENCE, 1995, 331 : 88 - 93
  • [9] Is benzene distorted on Rh(111)?
    Univ of Dublin, Dublin, Ireland
    Surf Sci, pt A (88-93):
  • [10] OBSERVATION OF LOW-ENERGY PHONONS IN SPINEL
    THOMPSON, P
    GRIMES, NW
    SOLID STATE COMMUNICATIONS, 1978, 25 (08) : 609 - 611
12345