KINETIC-PARAMETERS OF THERMAL-DECOMPOSITION OF THIOCYANATOBISMUTHATES(III) .3. AMMONIUM-SALTS

被引：0

作者：

KOBYLECKA, J ^{[1
]}

PTASZYNSKI, B ^{[1
]}

机构：

[1] TECH UNIV LODZ,INST GEN CHEM,PL-90924 LODZ,POLAND

来源：

THERMOCHIMICA ACTA | 1992年 / 209卷

关键词：

D O I：

10.1016/0040-6031(92)80194-2

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Kinetic parameters of thermal decomposition of thiocyanatobismuthates(III) of formulae (NH4)3[Bi(SCN)6], (NH4)2M[Bi(SCN)6] (where M is Li, Na, K, Rb) and NH4Ca[Bi(SCN)6].5H2O have been determined. The thermal stabilities (expressed by initial decomposition temperature and activation energy of the first step of decomposition) of thiocyanatobismuthates(III) containing alkali metal and ammonium group are compared with those of alkali metals in the outer sphere.

引用

页码：161 / 168

页数：8

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