A NEW LIGAND FOR THE SELF ASSEMBLY OF STARBURST COORDINATION OLIGOMERS AND POLYMERS

被引：60
|
作者：
CONSTABLE, EC
THOMPSON, AMWC
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 08期
关键词：
D O I：
10.1039/c39920000617
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The coordination properties of the tridentate ligand 2,2' : 6',2"-terpyridine (tpy) make it an ideal structural unit to control the assembly of coordination oligomers and polymers, and the new ligand 1,3,5-tris[4'-(2,2' : 6',2"-terpyridinyl)]benzene (ttpy) has been prepared as a building block for the assembly of coordination polymers, the complex [{(tpy)Ru}3(ttpy)][PF6]6 having been prepared; in the trinuclear complex, the three ruthenium(II) centres are equivalent and oxidise at the same potential.
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收藏
页码：617 / 619
页数：3
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