In this paper, SiO2-supported high effective Ziegler-Natta catalysts for copolymerization of propylene and ethylene were prepared. Possible high effective mechanisms were discussed. It was found that higher polymerization productivity, for instance 10kg(P)/ g(Ti). h, can be obtained by using TiCl4/Al(2)Et(3)Cl(3)/ SiO2 catalytic system.