STUDIES ON SOLID-STATE REACTIONS OF COORDINATION-COMPOUNDS .71. SOLID-STATE REACTIONS OF O-AMINOBENZOIC ACID WITH COPPER (II) ACETATE AND FORMATE AT ROOM-TEMPERATURE

被引:0
|
作者
ZHENG, LM [1 ]
LIN, JJ [1 ]
FU, Y [1 ]
XIN, XQ [1 ]
机构
[1] NANJING UNIV,DEPT CHEM,NANJING 210008,PEOPLES R CHINA
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关键词
SOLID STATE REACTION; O-AMINOBENZOIC ACID; COPPER ACETATE; COPPER FORMATE; ELECTRICAL CONDUCTIVITY;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Solid state reactions of o-aminobenzoic acid (HOAB) with Cu (OAc)2. H2O, Cu(HCOO)2. 4H2O, anhydrous Cu (OAc)2 and Cu(HCOO)2 at room or close to room temperature have been investigated. The product Cu(OAB)2 with a high yield was synthesized very conveniently compared with the solution phase method. The kinetic behavior was studied by means of the isothermal electrical conductivity measurement. The reactivity was found to decrease in the order: Cu(OAc)2. H2O>Cu (OAc)2>Cu(HCOO)2. 4H2O>Cu(HCOO)2, which was attributable to the crystal structures of the copper salts.
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页码:45 / 49
页数:5
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