PREPARATION, CHARACTERIZATION, AND 2ND-HARMONIC GENERATION OF A LANGMUIR-BLODGETT-FILM BASED ON A RARE-EARTH COORDINATION COMPOUND

被引：48
|
作者：
WANG, KZ
HUANG, CH
XU, GX
XU, Y
LIU, YQ
ZHU, DB
ZHAO, XS
XIE, XM
WU, NZ
机构：
[1] BEIJING UNIV,STATE KEY LAB RARE EARTH MAT CHEM,BEIJING 100871,PEOPLES R CHINA
[2] ACAD SINICA,INST CHEM,BEIJING 100080,PEOPLES R CHINA
[3] BEIJING UNIV,DEPT CHEM,BEIJING 100871,PEOPLES R CHINA
来源：
CHEMISTRY OF MATERIALS | 1994年 / 6卷 / 11期
关键词：
D O I：
10.1021/cm00047a017
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The rare-earth coordination compound (E)-N-hexadecyl-4-(2-(dimethylamino)phenyl)-ethenyl)pyridinium tetrakis(1-phenyl-3-methyl-4-benzoyl-5-pyrazolonato)dysprosium(III) was synthesized. The LB films were prepared and characterized by UV-vis, IR, X-ray photoelectron spectroscopy, and low-angle X-ray diffraction. High-quality LB films up to 50 layers on the hydrophilic substrates of quartz, calcium fluoride and glass were obtained. From the second-harmonic generation measurement, second-order molecular hyperpolarizability beta of the dysprosium complex was estimated to be about (6.6-9.3) x 10(-28) esu.
引用
收藏
页码：1986 / 1989
页数：4
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