SURFACE-ENHANCED RAMAN-SCATTERING SPECTRA OF PYRIDINE ADSORBED ON NICKEL

被引：22
|
作者：
ARAMAKI, K
YAMADA, M
JUN, UH
NISHIHARA, H
机构：
[1] Department of Chemistry, Faculty of Science and Technology, Keio University, Kohoku-ku, Yokohama 223
来源：
JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1991年 / 138卷 / 11期
关键词：
D O I：
10.1149/1.2085418
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Adsorption and orientation modes of pyridine adsorbed on nickel in 0.1M KCl at pH 3.5 are discussed based on surface-enhanced Raman scattering (SERS) spectroscopy. The SERS spectra of pyridine adsorbed on nickel were recorded on a Raman spectrometer with a SERS-active silver electrode covered with a thin layer of electrodeposited nickel. It is concluded that a pyridine molecule is perpendicularly chemisorbed on the nickel surface by the formation of a nickel-nitrogen sigma-bond.
引用
收藏
页码：3389 / 3393
页数：5
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