REACTION-MECHANISM OF CELLULOSE WITH EPOXY COMPOUNDS IN THE PRESENCE OF TERTIARY-AMINES

被引：0

作者：

ZEMAITAITIS, A

机构：

来源：

CELLULOSE CHEMISTRY AND TECHNOLOGY | 1992年 / 26卷 / 01期

关键词：

D O I：

暂无

中图分类号：

TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];

学科分类号：

0805 ; 080502 ; 0822 ;

摘要：

Reaction of various monoepoxides with cellulose in the presence of tertiary amines has been studied. With tertiary amines as a catalyst, at lower temperatures, epoxy compounds displayed greater reactivity than in the presence of sodium hydroxide. Qualitative and quantitative investigation of reaction mixtures epoxy compounds: tertiary amines: water by alkylation of cellulose showed that, during the reaction, quaternary ammonium base was formed. Tetraalkylammonium cellulosates further prepared in reaction mixtures are highly reactive intermediates for the preparation of cellulose ethers.

引用

页码：19 / 31

页数：13

共 50 条

[1] MECHANISM OF ALCOHOL ACYLATION REACTION IN PRESENCE OF TERTIARY-AMINES IN A NONPOLAR MEDIUM
BOGATKOV, SV
GOLOVINA, ZP
CHERKASOVA, EM
[J]. DOKLADY AKADEMII NAUK SSSR, 1976, 229 (01): : 98 - 101
[2] ON THE MECHANISM OF MESYLATION OF PHENOLS IN THE PRESENCE OF TERTIARY-AMINES
SKRYPNIK, IG
BEZRODNYI, VP
[J]. DOKLADY AKADEMII NAUK SSSR, 1982, 266 (03): : 642 - 645
[3] REACTION-KINETICS OF URETHANE FORMATION IN PRESENCE OF METAL-COMPOUNDS AND TERTIARY-AMINES
BAKALO, LA
SIROTINS.AL
LIPATOVA, TE
BLAGONRA.AA
PRONINA, IA
[J]. VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1973, 15 (01): : 91 - 95
[4] REACTION OF TERTIARY-AMINES WITH BROMOCYANINE AND WATER IN PRESENCE OF INORGANIC BASES
RONSCH, H
[J]. JOURNAL FUR PRAKTISCHE CHEMIE, 1972, 314 (02): : 382 - &
[5] THE REACTION OF TERTIARY-AMINES WITH ELECTROPHILIC REAGENTS .1. THE REACTION OF TERTIARY-AMINES WITH ARENESULFONYL CHLORIDES
SHIRAISHI, S
TAKAYAMA, T
[J]. NIPPON KAGAKU KAISHI, 1984, (08) : 1279 - 1286
[6] KINETICS AND KNOEVENAGEL REACTION-MECHANISM IN BENZENE .1. REACTION OF MALONITRILE AND (+)3-METHYL-CYCLOHEXANONE IN THE PRESENCE OF PURE SECONDARY AND TERTIARY-AMINES OR AMINES IN A MIXTURE WITH CARBOXYLIC-ACIDS
GUYOT, J
KERGOMARD, A
[J]. TETRAHEDRON, 1983, 39 (07) : 1161 - 1166
[7] ROLE OF PROTON-DONOR COMPOUNDS IN INITIATION OF THE POLYMERIZATION OF EPOXY COMPOUNDS BY TERTIARY-AMINES
KUSHCH, PP
KOMAROV, BA
ROZENBERG, BA
[J]. VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1979, 21 (08): : 1697 - 1703
[8] POLYMERIZATION OF MALEIMIDES IN THE PRESENCE OF TERTIARY-AMINES
IVANOV, AA
PRIMELYES, E
[J]. VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1984, 26 (06): : 1300 - 1305
[9] STUDY OF REACTION-MECHANISM BETWEEN CHINOBROMIC COMPOUNDS AND AMINES
VOLODKIN, AA
SOLODOVN.SP
RASULEVA, DK
PROKOFEV, AI
ERSHOV, VV
BUBNOV, NN
KUKES, SG
[J]. IZVESTIYA AKADEMII NAUK SSSR-SERIYA KHIMICHESKAYA, 1972, (05): : 1212 - &
[10] TERTIARY-AMINES QUARTERNIZATION REACTION BY CHLOROALKANES
SHAKHOVTSEVA, GA
ZUEV, VM
FILIMONOV, VA
FAINSHTEIN, IZ
[J]. KHIMICHESKAYA PROMYSHLENNOST, 1991, (06): : 336 - 337

← 1 2 3 4 5 →