COBALT SCHIFF-BASE COMPLEX CATALYZED DEHYDROGENATION OF AMINES WITH TERT-BUTYL HYDROPEROXIDE

被引：26
|
作者：
MARUYAMA, K
KUSUKAWA, T
HIGUCHI, Y
NISHINAGA, A
机构：
来源：
CHEMISTRY LETTERS | 1991年 / 07期
关键词：
D O I：
10.1246/cl.1991.1093
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cobalt Schiff base complex catalyzed oxidation of secondary aromatic amines with t-butyl hydroperoxide resulted selectively in dehydrogenation to give the corresponding imines. Proposed mechanism involves electron transfer from the nitrogen atom in the substrate to t-butyloxyl or t-butylperoxyl radical produced in situ from a t-butylperoxocobalt(III) complex intermediate.
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页码：1093 / 1096
页数：4
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