THE PREDICTION OF THE F-19 NMR SIGNAL POSITIONS OF FLUOROALKENES USING STATISTICAL-METHODS

被引：7

作者：

JETTON, RE

NANNEY, JR

MAHAFFY, CAL

机构：

[1] AUBURN UNIV,DEPT CHEM,MONTGOMERY,AL 36117

[2] AUBURN UNIV,DEPT MATH,MONTGOMERY,AL 36117

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 72卷 / 01期

关键词：

NMR SIGNAL POSITIONS; FLUOROALKENES; STATISTICAL METHODS; STATISTICAL SUBSTITUENT CHEMICAL SHIFT VALUES;

D O I：

10.1016/0022-1139(94)03188-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

F-19 NMR data for fluoroalkenes have been analyzed by the use of statistical substituent chemical shift (SSCS) values and SSCS values in combination with interaction factors. The correlation coefficient of observed versus predicted signal position when SSCS values alone are used is r=0.960 with a standard deviation s=10.0 ppm, whereas r=0.997 and s=2.8 ppm when SSCS values are used together with 2,3-, 2,4- and 3,4-interaction factors.

引用

页码：121 / 133

页数：13

共 50 条

[1] The prediction of the B-11 NMR signal positions of trigonal boranes using statistical methods
Nanney, JR
Jetton, RE
Mahaffy, CAL
ELECTRONIC JOURNAL OF THEORETICAL CHEMISTRY, 1997, 2 : 24 - 48
[2] THE PREDICTION OF THE F-19 NMR-SPECTRA OF FLUOROARENES USING STATISTICAL SUBSTITUENT CHEMICAL-SHIFT VALUES
MAHAFFY, CAL
NANNEY, JR
JOURNAL OF FLUORINE CHEMISTRY, 1994, 67 (01) : 67 - 74
[3] VISIBILITY PREDICTION BY STATISTICAL-METHODS
COURT, A
LIN, GY
ZETSCHE, S
BULLETIN OF THE AMERICAN METEOROLOGICAL SOCIETY, 1981, 62 (06) : 885 - 885
[4] THE STATISTICAL PREDICTION OF THE F-19-NMR SIGNAL POSITION IN SUBSTITUTED FLUOROARENETRICARBONYLCHROMIUM COMPLEXES
NANNEY, JR
MAHAFFY, CAL
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 : 85 - FLUO
[5] MEASUREMENT OF CYTOSOLIC CALCIUM USING F-19 NMR
MURPHY, E
LEVY, L
RAJU, B
STEENBERGEN, C
GERIG, JT
SINGH, P
LONDON, RE
ENVIRONMENTAL HEALTH PERSPECTIVES, 1990, 84 : 95 - 98
[6] THE STATISTICAL PREDICTION OF THE C-13-NMR SIGNAL POSITIONS IN ARENETRICARBONYLCHROMIUM COMPLEXES USING STATISTICAL SCS VALUES
MAHAFFY, CAL
NANNEY, JR
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 594 - INOR
[7] INFRARED VISIBILITY PREDICTION BY STATISTICAL-METHODS
COURT, A
LIN, GY
ZETSCHE, S
PURE AND APPLIED GEOPHYSICS, 1982, 120 (02) : 203 - 210
[8] PREDICTION OF SERVICE LIFE OF SPUR GEARS USING STATISTICAL-METHODS
GLODEZ, S
PEHAN, S
FLASKER, J
STROJNISKI VESTNIK-JOURNAL OF MECHANICAL ENGINEERING, 1994, 40 (11-12): : 393 - 400
[9] THE PREDICTION OF THE F-19 NMR-SPECTRA OF FLUOROARENES USING MATHEMATICAL-MODELING TECHNIQUES
NANNEY, JR
TRAYLOR, AK
MAHAFFY, CAL
JOURNAL OF FLUORINE CHEMISTRY, 1993, 64 (03) : 217 - 253
[10] F-19 NMR INVESTIGATIONS OF MEMBRANES
HO, C
DOWD, SR
POST, JFM
CURRENT TOPICS IN BIOENERGETICS, 1985, 14 : 53 - 95

← 1 2 3 4 5 →