OXYGEN-TRANSFER BY DISSOCIATIVE ELECTRON-TRANSFER - REACTION OF TETRANITROMETHANE WITH DIAZO-COMPOUNDS AND SULFIDES

被引：10

作者：

ADAM, W

NUNEZ, EG

机构：

[1] Institute of Organic Chemistry, University of Würzburg, 8700 Würzburg, Am Hubland, W

来源：

TETRAHEDRON | 1991年 / 47卷 / 23期

关键词：

D O I：

10.1016/S0040-4020(01)80902-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the absence of oxygen, diphenyldiazomethane is oxidized by tetranitromethane (TNM) to afford benzophenone and products derived from the diazoalkane radical cation, in yields strongly dependent on the reaction conditions. Sulfides were also found to undergo this oxygen transfer process with TNM. An initial dissociative electron transfer step is postulated to account for the observed results.

引用

页码：3773 / 3778

页数：6

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