PREPARATION OF BATIO3 THIN-FILMS BY METALORGANIC CHEMICAL-VAPOR-DEPOSITION USING ULTRASONIC SPRAYING

Ferroelectric BaTiO3 thin films were fabricated by metalorganic chemical vapor deposition (MOCVD) at atmospheric pressure. The ultrasonic spraying technique has been used to carry the source materials. The common solutions of barium-diethylhexanoate and diisopropoxy-titanium-bis-acetylacetonate in n-butanol were used as the starting materials. Since the concentration of sources can be controlled in the common solution, this method is more simple and precise than other CVD processes. The films had(110)preferred orientation with increasing temperature. The dielectric constant (epsilon) and the loss factor (tan delta) of thin film deposited at 550 degrees C were about 250 and 0.1, respectively. The leakage current density was 10(-5) A/cm(2) at 0.1 MV/cm.