HYDROGENATION OF CARBON-MONOXIDE AND ETHENE OVER NI-DOPED SUPPORTED PT CATALYSTS

被引:2
|
作者
EDER, F
LERCHER, JA
机构
[1] UNIV TWENTE,DEPT CHEM TECHNOL,7500 AE ENSCHEDE,NETHERLANDS
[2] UNIV TWENTE,CHRISTIAN DOPPLER LAB HETEROGENEOUS CATALYSIS,7500 AE ENSCHEDE,NETHERLANDS
关键词
D O I
10.1039/ft9949002977
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The hydrogenation of ethene and carbon monoxide over Ni-doped Pt catalysts has been investigated. The addition of Ni to Pt significantly enhanced the catalytic activity of the silica-supported catalysts, while it had little effect on the titania-supported catalysts. For both reactions, however, the activity of the titania-supported catalysts was substantially higher than that of the silica-supported catalysts. The variations in the catalytic activities are explained in terms of a lower sorption constant of ethene and an improved activation of CO, respectively.
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页码:2977 / 2979
页数:3
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