CRYSTALLIZATION OF WATER IN SWOLLEN POLY(VINYL ALCOHOL) POLY(VINYL PYRROLIDONE) BLENDS

被引：17
|
作者：
RAULT, J
PING, ZH
NGUYEN, QT
机构：
[1] FUDAN UNIV,DEPT POLYMER MAT,SHANGHAI 200433,PEOPLES R CHINA
[2] ECOLE NATL SUPER IND CHIM,INST NATL POLYTECH LORRAINE,LCPM,CNRS,URA 494,F-54001 NANCY,FRANCE
来源：
POLYMER BULLETIN | 1995年 / 35卷 / 05期
关键词：
D O I：
10.1007/BF00324121
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Water molecules sorbed in pure poly(vinyl alcohol) and poly(vinyl pyrrolidone), as well as in their blends is found to be only partially crystallizable. The fraction of non-crystalizable water is shown to vary with the blend composition. Such variation is explained by the newly proposed Tg-regulation effect when the swollen blend materials is cooled down. A part of the sorbed water cannot crystallize due to the fact that during cooling the amorphous polmer-water phase is frozen before the water crystallization temperature is reached.
引用
收藏
页码：649 / 652
页数：4
相关论文
共 50 条
  • [1] Characterization of hydrogel blends of poly(vinyl pyrrolidone) and poly(vinyl alcohol vinyl acetate)
    CauichRodriguez, JV
    Deb, S
    Smith, R
    [J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 1996, 7 (05) : 269 - 272
  • [2] Viscometric and ultrasonic studies of blends of poly(vinyl pyrrolidone) and poly(vinyl alcohol)
    Rao, RV
    Iatha, P
    [J]. JOURNAL OF MATERIALS SCIENCE LETTERS, 1999, 18 (06) : 457 - 459
  • [3] MISCIBILITY AND ORIENTATION BEHAVIOR OF POLY(VINYL ALCOHOL) POLY(VINYL PYRROLIDONE) BLENDS
    NISHIO, Y
    HARATANI, T
    TAKAHASHI, T
    [J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1990, 28 (03) : 355 - 376
  • [4] Poly(vinyl alcohol) and poly(vinyl pyrrolidone) blends: Miscibility, microheterogeneity and free volume change
    Cassu, SN
    Felisberti, MI
    [J]. POLYMER, 1997, 38 (15) : 3907 - 3911
  • [5] Surface study of poly(vinyl alcohol) and poly(N-vinyl-2-pyrrolidone) miscible blends
    Li, L
    Chan, CM
    Weng, LT
    [J]. ANTEC'97 - PLASTICS SAVING PLANET EARTH, CONFERENCE PROCEEDINGS, VOLS 1 - 3, 1997, : 2531 - 2534
  • [6] Dynamic mechanical characterization of hydrogel blends of poly(vinyl alcohol-vinyl acetate) with poly(acrylic acid) or poly(vinyl pyrrolidone)
    CauichRodriguez, JV
    Deb, S
    Smith, R
    [J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 1996, 7 (06) : 349 - 353
  • [7] Characterization of Associating Hydrogels of Poly(vinyl alcohol) and Poly(vinyl pyrrolidone)
    Liu, X.
    Fussell, G.
    Marcolongo, M.
    Lowman, A. M.
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 112 (01) : 541 - 549
  • [8] Miscibility and crystallization of poly(β-hydroxybutyrate)/poly(vinyl acetate-co-vinyl alcohol) blends
    Xing, PX
    Ai, X
    Dong, LS
    Feng, ZL
    [J]. MACROMOLECULES, 1998, 31 (20) : 6898 - 6907
  • [9] Poly(vinyl alcohol)/poly(vinyl pyrrolidone) hydrogels for the cleaning of art
    Bonelli, Nicole
    Poggi, Giovanna
    Chelazzi, David
    Giorgi, Rodorico
    Baglioni, Piero
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2019, 536 : 339 - 348
  • [10] Release of salicylic acid through poly(vinyl alcohol/poly(vinyl pyrrolidone) and poly(vinyl alcohol-g-N-vinyl-2-pyrrolidone) membranes
    Sanli, Oya
    Orhan, Emel
    Asman, Gulsen
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 102 (02) : 1244 - 1253
12345