THE COPPER(II) COMPLEX WITH THE IMIDAZOLE-BOUND HISTAMINE DERIVATIVE OF BETA-CYCLODEXTRIN AS A POWERFUL CHIRAL DISCRIMINATING AGENT

被引：53

作者：

CUCINOTTA, V ^{[1
]}

DALESSANDRO, F ^{[1
]}

IMPELLIZZERI, G ^{[1
]}

VECCHIO, G ^{[1
]}

机构：

[1] CNR,IST STUDIO SOSTANZE NAT INTERESSE ALIMENTARE & CHIM FARMACEUT,I-95125 CATANIA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 23期

关键词：

D O I：

10.1039/c39920001743

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The newly synthesized 6-derivative of beta-cyclodextrin with histamine, bound through the N-1 of imidazole was used as a ligand for copper(II) ion, the ligand being characterized by NMR spectroscopy and the copper(II) complex by EPR spectroscopy; the complex was used in chiral ligand exchange chromatography and was able to separate L- and D-tryptophan.

引用

页码：1743 / 1745

页数：3

共 7 条

[1] CHIRAL RECOGNITION AND SEPARATION OF AMINO-ACIDS BY MEANS OF A COPPER(II) COMPLEX OF HISTAMINE MONOFUNCTIONALIZED BETA-CYCLODEXTRIN
CORRADINI, R
DOSSENA, A
IMPELLIZZERI, G
MACCARRONE, G
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RIZZARELLI, E
SARTOR, G
VECCHIO, G
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (22) : 10267 - 10274
[2] Chiral recognition by the copper(II) complex of 6-deoxy-6-N-(2-methylaminopyridine)-beta-cyclodextrin
Bonomo, RP
Cucinotta, V
DAlessandro, F
Impellizzeri, G
Maccarrone, G
Rizzarelli, E
Vecchio, G
Carima, L
Corradini, R
Sartor, G
Marchelli, R
CHIRALITY, 1997, 9 (04) : 341 - 349
[3] Chiral recognition and separation of amino acids by means of a copper(II) complex of histamine monofunctionalized β-cyclodextrin
1600, ACS, Washington, DC, USA (116):
[4] STRUCTURE DETERMINATION OF COPPER(II)-BETA-CYCLODEXTRIN COMPLEX BY FOURIER-TRANSFORM INFRARED-SPECTROSCOPY
EGYED, O
WEISZFEILER, V
VIBRATIONAL SPECTROSCOPY, 1994, 7 (01) : 73 - 77
[5] Chiral copper(II) complex based on natural product rosin derivative as promising antitumour agent
Fei, Bao-Li
Huang, Zhi-Xiang
Xu, Wu-Shuang
Li, Dong-Dong
Lu, Yang
Gao, Wei-Lin
Zhao, Yue
Zhang, Yu
Liu, Qing-Bo
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY, 2016, 160 : 43 - 52
[6] CONFORMATIONAL FEATURES AND COORDINATION PROPERTIES OF FUNCTIONALIZED CYCLODEXTRINS - FORMATION, STABILITY, AND STRUCTURE OF PROTON AND COPPER(II) COMPLEXES OF HISTAMINE-BEARING BETA-CYCLODEXTRIN IN AQUEOUS-SOLUTION
BONOMO, RP
CUCINOTTA, V
DALESSANDRO, F
IMPELLIZZERI, G
MACCARRONE, G
VECCHIO, G
RIZZARELLI, E
INORGANIC CHEMISTRY, 1991, 30 (13) : 2708 - 2713
[7] COORDINATION PROPERTIES OF 6-DEOXY-6-[1-(2-AMINO) ETHYLAMINO]-BETA-CYCLODEXTRIN AND THE ABILITY OF ITS COPPER(II) COMPLEX TO RECOGNIZE AND SEPARATE AMINO-ACID ENANTIOMERIC PAIRS
BONOMO, RP
CUCINOTTA, V
DALLESSANDRO, F
IMPELLIZZERI, G
MACCARRONE, G
RIZZARELLI, E
JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1993, 15 (02): : 167 - 180

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