Study of Acoustic Parameters of Binary Mixtures of Cyclohexane with 2-Methoxyethanol

被引:0
|
作者
Bhavani, M. Durga [1 ]
Ratnakar, A. [1 ]
Satyaveni, S. [2 ]
机构
[1] VR Siddhartha Engn Coll Autonomous, Dept Chem, Vijayawada 520007, AP, India
[2] Univ Coll Engn, Dept Chem, JNTU, Kakinada, Andhra Pradesh, India
关键词
Cyclohexane; 2-Methoxyethanol; Ultrasonic velocity; Density; Free length; Free volume;
D O I
暂无
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The interactions existing between components of the binary mixtures, namely cyclohexane and 2-methoxyethanol are found to be affected by the ultrasonic wave with a frequency of 2 MHz. Using the experimental data, some thermodynamic and acoustic parameters are computed at different temperatures over the entire composition range. Among the parameters are intermolecular free length (L-f), free volume (V-f), relaxation time (tau), acoustic impedance (Z), Rao's constant (R) and Wada's constant (W). Variations in these parameters at different concentrations of the components are non-linear and are explained based on structural changes taking place in the solutions. Variations in all the parameters play a significant role in arriving at the possible interactions existing between solute and solvent.
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页码:893 / 900
页数:8
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