SYNTHESIS AND REACTIONS OF N,N-DICHLOROPERFLUOROALKANESULFONYLAMIDES

被引：11
|
作者：
ZHU, SZ
ZHOU, CM
LI, AW
XU, B
机构：
[1] Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1994年 / 67卷 / 01期
关键词：
D O I：
10.1016/0022-1139(93)03034-J
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of N,N-dichloroperfluoroalkanesulfonylamides with alkenes, benzene, dimethyl sulfide and dimethyl sulfoxide in the presence of zinc dust gave addition or insertion products via the fluoroalkanesulfonylnitrene intermediate. On heating RfSO2NCl2 in the presence of alkene without zinc, 1:1 addition products were formed via a free-radical mechanism.
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页码：7 / 8
页数：2
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