CRYSTAL-STRUCTURE OF POLYMERIC DI-MU(1,3)-AZIDODIPYRIDINEMANGANESE(II) - [MN(PY)2(N3)2]

被引：0
|
作者：
GOHER, MAS [1 ]
MAUTNER, FA [1 ]
机构：
[1] GRAZ TECH UNIV,INST PHYS & THEORET CHEM,A-8010 GRAZ,AUSTRIA
来源：
CROATICA CHEMICA ACTA | 1991年 / 63卷 / 04期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structure of a 1:2 complex of manganese(II) azide with pyridine has been determined by X-ray crystallography. The crystals are tetragonal and belong to the space group I 4(1)/a, with a = 1551.7(4), c = 1003.1(1) pm and Z = 8. The structure has been refined to R = 0.67 for 1152 observed MoK-alpha diffractometer data. The manganese atom is octahedrally coordinated by six ligand nitrogen atoms at distances of 219.5(5), 221.7(4) and 225.9(3) pm. These octahedra are linked together by the mu(1,3)-azido ligands to form a three dimensional network. The azide groups are almost linear and appear to be symmetrical, the N-N distances being 115.1(6) and 117.0(5) pm. The symmetry of the azido ligands is confirmed by disappearance of the nu(s)N3 mode from the infrared spectrum.
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页码：559 / 564
页数：6
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