The reactions of U-Zr alloys with nitrogen were studied at temperatures ranging from 873 to 1273 K. Electron probe microanalysis, wide angle and microbeam X-ray diffraction techniques were applied for the identification of reaction products. Adherent multi-layered scales were formed during the anneals under nitrogen pressures of 0.19 and 20 kPa. They were mainly composed of U2N3, ZrN and alpha-Zr(N). The scale thickness and morphology depended on the alloy compositions and temperatures.
机构:
Japan Atom Energy Res Inst, Dept Chem & Fuel Res, Tokai, Ibaraki 31911, JapanJapan Atom Energy Res Inst, Dept Chem & Fuel Res, Tokai, Ibaraki 31911, Japan
Akabori, M
Itoh, A
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Japan Atom Energy Res Inst, Dept Chem & Fuel Res, Tokai, Ibaraki 31911, JapanJapan Atom Energy Res Inst, Dept Chem & Fuel Res, Tokai, Ibaraki 31911, Japan
Itoh, A
Ogawa, T
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Japan Atom Energy Res Inst, Dept Chem & Fuel Res, Tokai, Ibaraki 31911, JapanJapan Atom Energy Res Inst, Dept Chem & Fuel Res, Tokai, Ibaraki 31911, Japan