PREDICTION OF GAS-CHROMATOGRAPHY SOLUTE ACTIVITY-COEFFICIENTS IN MIXED STATIONARY PHASES BASED ON THE WILSON EQUATION

被引：28
|
作者：
COMOR, JJ
KOPECNI, MM
机构：
[1] Chemical Dynamics Laboratory, Boris Kidric Institute of Nuclear Sciences, 11001 Belgrade
来源：
ANALYTICAL CHEMISTRY | 1990年 / 62卷 / 10期
关键词：
D O I：
10.1021/ac00209a004
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Gas chromatography based activity and partition coefficients are reported for nine solutes, including aliphatic, allcycllc, chlorinated aliphatic, and aromatic solutes, in two mixed stationary phases, (a) N,N-dlbutyl-2-ethylhexanamlde NV,N-dlbutyl-2,2-dlmethylbutanamlde and (b) N,N-dlbutyl-2-ethylhexanamlde + dodecanol, In the mole fraction region from 0 to 1, for five temperatures spanning from 298.15 to 338.15 K. The Infinite dilution activity coefficients of solutes in mixed solvents can be accurately described by a simple, thermodynamically founded, four-parameter equation, derived from the expression originally reported by G. M. Wilson. © 1990, American Chemical Society. All rights reserved.
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页码：991 / 994
页数：4
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