STUDY ON THE STRUCTURE OF POLY(OXY-2,6-DIMETHYL-1,4-PHENYLENE) BY H-1-NMR SPECTROSCOPIC MICROANALYSIS

被引：1
|
作者：
TAKAYAMA, S [1 ]
MITUI, A [1 ]
TAKEDA, K [1 ]
机构：
[1] SIBAURA INST TECHNOL,DEPT MET ENGN,MINATO KU,TOKYO 108,JAPAN
来源：
KOBUNSHI RONBUNSHU | 1994年 / 51卷 / 07期
关键词：
POLY(OXY-2,6-DIMETHYL-1,4-PHENYLENE); H-1; NMR; 2,6-DIMETHYLPHENOL; DIBUTHYLAMINO GROUP;
D O I：
10.1295/koron.51.479
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The sturcture of poly(oxy-2,6-dimethyl-1,4-phenylene) (PPE) was studied by H-1 NMR spectroscopic microanalysis. Several model compounds were prepared in advance in order to compare their NMR spectroscopy to that of PPE. As a result, PPE had a repetitive unit of 2,6-dimetylphenol in the main which is synthesized by head-to-tail porimerization. The structure made by Fries type rearrangement which was generally observed in PPE was not observed. Dibutylamino radical was detected in the polymer structure and their H-1 NMR signals were observed in the range of 1.3 ppm to 2.3 ppm. The amine structure was thought to be introduced to the polymer in the polymerization.
引用
收藏
页码：479 / 485
页数：7
相关论文
共 50 条
12345