INFRARED-ABSORPTION IN HYDROGEN-BONDED COMPLEXES AND ABSORPTION OF AN EXCESS ELECTRON IN HYDROGEN-BONDED SOLVENTS

被引：7
|
作者：
ABRAMCZYK, H
机构：
[1] Institute of Applied Radiation Chemistry, Technical University, 93-590 Łódź
来源：
VIBRATIONAL SPECTROSCOPY | 1993年 / 5卷 / 01期
关键词：
INFRARED SPECTROMETRY; EXCESS-ELECTRONS; HYDROGEN-BONDED COMPLEXES; HYDROGEN-BONDED SOLVENTS; INFRARED ABSORPTION;
D O I：
10.1016/0924-2031(93)87060-7
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A comparison was made between the theories of IR absorption in hydrogen-bonded complexes and near-IR and visible absorption of an excess electron in hydrogen-bonded solvents. The near-IR and visible absorption spectra of excess electrons in water, alcohols, amines and alkanes were calculated in terms of electron-vibron coupling. The role of the hydrogen bond on electron stabilization and solvation is discussed.
引用
收藏
页码：109 / 117
页数：9
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