ISOBARIC VAPOR-LIQUID-EQUILIBRIA FOR THE BINARY-SYSTEMS CH3SIHCL2 WITH (CH3)3SICL, (CH3)2SICL2, CH3SICL3, OR SICL4

This paper reports isobaric vapor-liquid equilibrium (VLE) data for four binary systems containing dichloromethyisilane, CH3SIHCl2, and chlorotrimethyl-, dichlorodimethyl-, trichloromethyl-, or tetrachlorosilane, (CH3)4-nSICIn (n = 1-4). The VLE data were determined ebulliometrically at atmospheric pressure, and the experimental temperatures were corrected for 760 mmHg. The pure component vapor pressures were calculated using literature Antoine constants. The VLE data were then correlated by means of the Wilson, nonrandom two-liquid (NRTL), and Gothard equations.