STRUCTURE AND COMPATIBILITY OF POLY(VINYL ALCOHOL)-SILK FIBROIN (PVA/SF) BLEND FILMS

The structure and compatibility of poly(vinyl alcohol)-silk fibroin (PVA/SF) blend films were analyzed by differential scanning calorimetry (DSC), thermomechanical (TMA) and thermogravimetric (TGA) analysis, x-ray diffractometry, and scanning (SEM) and transmission (TEM) electron microscopy. DSC curves of PVA/SF blend films showed a major endothermic peak at 220 degrees C, along with a peak at 280 degrees C. These endotherms were assigned to the thermal decomposition of the ordered PVA elements and to the thermal degradation of silk fibroin, respectively. The PVA/SF blends behaved in a manner intermediate to the pure components, as suggested by both contraction-expansion and sample weight retention properties recorded by TMA and TGA measurements. The IR absorption spectra of the blends were identified as purely a composite of the absorption bands characteristic of both PVA and SF pure polymers. The X-ray diffraction patterns of PVA/SF blends showed overlapping spacings due to PVA and SF. A dispersed phase formed by spherical particles of 3-7 mu m diameter was observed by SEM and TEM. All these findings suggest that PVA and SF are incompatible. (C) 1994 John Wiley and Sons, Inc.