PHOTOCHEMICAL-REACTIONS OF TETRAMETHYLSTANNANE ISOLATED IN LOW-TEMPERATURE ARGON MATRIX

被引：5

作者：

OBAYASHI, C ^{[1
]}

SATO, H ^{[1
]}

TOMINAGA, T ^{[1
]}

机构：

[1] SCI UNIV TOKYO,FAC SCI,DEPT CHEM,TOKYO 162,JAPAN

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-LETTERS | 1992年 / 164卷 / 06期

关键词：

D O I：

10.1007/BF02168268

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Photolytic products of tetramethylstannane in low temperature argon matrix were studied by Mossbauer, IR, and UV spectroscopy. At an early stage of the reaction, an unstable tin compound possibly with a tin-carbon double bond was formed in low temperature argon matrix, which might not exist in ordinary conditions. In subsequent reactions, cyclic tin compounds with large quadrupole splittings might be produced.

引用

页码：365 / 372

页数：8

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