Synthesis and Study of the Rubidium Uranate Rb-4(UO2)(8)O-7(OH)(6)center dot H2O

被引：3
|
作者：
Chernorukov, N. G. [1 ]
Nipruk, O. V. [1 ]
Chernorukov, G. N. [1 ]
Kostrova, E. L. [1 ]
Chaplieva, K. A. [1 ]
机构：
[1] Lobachevsky State Univ, Pr Gagarina 23, Nizhnii Novgorod 603950, Russia
来源：
RADIOCHEMISTRY | 2015年 / 57卷 / 05期
关键词：
rubidium uranate; synthesis; X-ray diffraction; IR spectra; thermal analysis;
D O I：
10.1134/S1066362215050069
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Rubidium uranate Rb-4(UO2)(8)O-7(OH)(6)center dot H2O was prepared by the reaction of an aqueous solution of uranyl acetate with an aqueous solution of rubidium nitrate under hydrothermal conditions at 200 degrees C. The compound was studied by chemical analysis, X-ray diffraction, IR spectroscopy, and differential thermal analysis. The dehydration and thermal decomposition of the compound were studied.
引用
收藏
页码：488 / 491
页数：4
相关论文
共 50 条
  • [1] Synthesis and study of lead(II) uranate Pb(UO2)2O2(OH)2·H2O
    N. G. Chernorukov
    O. V. Nipruk
    R. V. Abrazheev
    K. A. Chaplieva
    Russian Journal of General Chemistry, 2016, 86 : 1987 - 1990
  • [2] Synthesis and study of lead(II) uranate Pb(UO2)2O2(OH)2•H2O
    Chernorukov, N. G.
    Nipruk, O. V.
    Abrazheev, R. V.
    Chaplieva, K. A.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2016, 86 (09) : 1987 - 1990
  • [3] Structural diversity of sheets in rubidium uranyl oxoselenates:: Synthesis and crystal structures of Rb2[(UO2)(SeO4)2(H2O)](H2O), Rb2[(UO2)2(SeO4)3(H2O)2](H2O)4, and Rb4[(UO2)3(SeO4)5(H2O)]
    Krivovichev, SV
    Kahlenberg, V
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (04): : 739 - 744
  • [4] Synthesis and Study of Rubidium Hexauranate Rb2[(UO2)6O3(OH)8]·6H2O and Products of Its Heat Decomposition
    O. V. Nipruk
    N. G. Chernorukov
    M. O. Bakhmetiev
    E. V. Elipasheva
    M. I. Lelet
    K. A. Chaplieva
    Russian Journal of General Chemistry, 2019, 89 : 1630 - 1636
  • [5] Synthesis and Study of Rubidium Hexauranate Rb2[(UO2)6O3(OH)8]•6H2O and Products of Its Heat Decomposition
    Nipruk, O., V
    Chernorukov, N. G.
    Bakhmetiev, M. O.
    Elipasheva, E., V
    Lelet, M., I
    Chaplieva, K. A.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2019, 89 (08) : 1630 - 1636
  • [6] Crystal chemistry of rubidium uranyl molybdates:: Crystal structures of Rb6[(UO2)(MoO4)4], Rb6[(UO2)2O(MoO4)4], Rb2[(UO2)(MoO4)2], Rb2[(UO2)2(MoO4)3] and Rb2[(UO2)6(MoO4)7(H2O)2]
    Krivovichev, SV
    Burns, PC
    JOURNAL OF SOLID STATE CHEMISTRY, 2002, 168 (01) : 245 - 258
  • [7] Rubidium uranyl phosphates and arsenates with polymeric tetrahedral anions: Syntheses and structures of Rb4[(UO2)6(P2O7)4(H2O)], Rb2[(UO2)3(P2O7)(P4O12)] and Rb[(UO2)2(AS3O10)]
    Alekseev, Evgeny V.
    Krivovichev, Sergey V.
    Depmeier, Wulf
    JOURNAL OF SOLID STATE CHEMISTRY, 2009, 182 (08) : 2074 - 2080
  • [8] Refinement of the crystal structure of billietite, Ba [(UO2)6 O4 (OH)6] (H2O)8
    Finch, Robert J.
    Burns, Peter C.
    Hawthorne, Frank C.
    Ewing, Rodney C.
    CANADIAN MINERALOGIST, 2006, 44 (05): : 1197 - 1205
  • [9] Synthesis and Characterization of Sodium and Potassium Uranates with the Compositions Na2[(UO2)6O4(OH)6] • 8H2O and K2[(UO2)6O4(OH)6] • 8H2O
    Nipruk, O. V.
    Chernorukov, G. N.
    Abrazheev, R. V.
    Kostrova, E. L.
    INORGANIC MATERIALS, 2017, 53 (08) : 816 - 819
  • [10] CRYSTAL-STRUCTURE OF CURITE, [PB6.56(H2O,OH)4] [(UO2)8O8(OH)6]2
    MEREITER, K
    TSCHERMAKS MINERALOGISCHE UND PETROGRAPHISCHE MITTEILUNGEN, 1979, 26 (04): : 279 - 292
12345