OPTICAL AND TRANSPORT-PROPERTIES OF NEW TRANSITION-METAL FLUORIDE GRAPHITE-INTERCALATION COMPOUNDS (GICS)

被引：2
|
作者：
AMINE, K
TRESSAUD, A
MAYORGA, SG
GRANNEC, J
HAGENMULLER, P
PIRAUX, L
ISSI, JP
NAKAJIMA, T
机构：
[1] UNIV BORDEAUX 1,CNRS,CHIM SOLIDE LAB,F-33405 TALENCE,FRANCE
[2] CATHOLIC UNIV LOUVAIN,UNITE PHYSICOCHIM & PHYS MAT,B-1348 LOUVAIN,BELGIUM
[3] KYOTO UNIV,FAC ENGN,DEPT IND CHEM,KYOTO 606,JAPAN
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1992年 / 57卷 / 1-3期
关键词：
D O I：
10.1016/S0022-1139(00)82814-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The intercalation process of some d-transition metal fluorides in graphite has been investigated using anhydrous liquid HF. C(x)MF(y) GICs have been obtained for M = Cr, Rh, Ir and Au. The charge transfer has been evaluated from optical reflectivity measurements. Comparison has been carried out between electrical conductivity obtained from optical data and from a contactless method. Results on the in-plane electrical resistivity and thermal conductivity are reported. All compounds exhibit a logarithmic resistivity divergence in the low-temperature range due to weak localization and carrier-carrier interaction effects for 2D metals.
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页码：35 / 43
页数：9
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