ALKALINE METAL FLUORIDES IN GRAPHITE - NEW CATALYSTS IN ORGANIC-SYNTHESIS .1. REACTIONS OF POLYFLUOROAROMATIC COMPOUNDS WITH O-NUCLEOPHILIC AND N-NUCLEOPHILIC AGENTS

被引:3
|
作者
AKSENOV, VV
VLASOV, VM
DANILKIN, VI
RODIONOV, PP
SHNITKO, GN
机构
[1] Institute of Organic Chemistry, Novosibirsk
关键词
D O I
10.1016/S0022-1139(00)81559-6
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The paper reports the use of new catalysts - alkaline metal fluorides in graphite of the general formula C8MF, where M=Li, Na, K, Rb or Cs, in the reactions of polyfluoroaromatic compounds with aromatic OH-acids and piperidine. These compounds are shown to have a high activity in the above processes, exceeding that of similar free fluorides of alkaline metals. © 1990.
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页码:57 / 73
页数:17
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