Synthesis, characterization, and X-ray crystal structure of tris(1,10-phenanthroline)nickel(II) perchlorate hemihydrate

被引：16
|
作者：
AbdelRahman, L
Battaglia, LP
Rizzoli, C
Sgarabotto, P
机构：
[1] Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, Centro di Studio per la Strutturistica Diffrattometrica del C. N. R., Università di Parma, Parma, I-43100, Viale delle Scienze
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1995年 / 25卷 / 10期
关键词：
phenanthroline complexes; polymorphism; racemization;
D O I：
10.1007/BF01665968
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound was synthesized and characterized by conventional methods and its X-ray crystal structure was determined. The complex crystallizes in the monoclinic space group C2/c with eight formula units in a cell of dimensions: a = 36.714(4), b = 15.746(2), c = 12.337(2) Angstrom; beta = 102.9(1)degrees. The structure is built up by alternate layers of octahedral [Ni(phen)(3)](2+) cations and perchlorate anions with water molecules which run in the direction of the a axis nearly parallel to the be plane.
引用
收藏
页码：629 / 632
页数：4
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