UV PHOTOELECTRON-SPECTROSCOPY OF POLY (1,1'-FERROCENEDIYL)

被引：10
|
作者：
SEKI, K [1 ]
TANAKA, H [1 ]
OHTA, T [1 ]
SANECHIKA, K [1 ]
YAMAMOTO, T [1 ]
机构：
[1] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,MIDORI KU,YOKOHAMA,KANAGAWA 227,JAPAN
来源：
CHEMICAL PHYSICS LETTERS | 1991年 / 178卷 / 2-3期
关键词：
D O I：
10.1016/0009-2614(91)87074-L
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
UV photoelectron spectra were measured for poly (1,1'-ferrocenediyl) (PF) synthesized in a well controlled way. The spectra are similar to those of ferrocene and 1,1'-biferrocene, indicating limited electron delocalization. The ionization threshold energy was found to be 5.1 eV. Comparison with related compounds and information from other techniques indicate that PF is a unique system with intermediate electron delocalization between highly delocalized pi-conjugated polymers and well localized systems such as vinyl polymers. The limited increase in electric conductivity upon acceptor doping is ascribed to ineffective hole transport rather than difficulty in hole creation.
引用
收藏
页码：311 / 316
页数：6
相关论文
共 50 条
  • [1] 1ST IONIZATION BAND OF 1,1-DIMETHYLSILAETHYLENE BY TRANSIENT PHOTOELECTRON-SPECTROSCOPY
    KOENIG, T
    MCKENNA, W
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (05) : 1212 - 1213
  • [2] SYSTEMATIC ORGANIC UV PHOTOELECTRON-SPECTROSCOPY
    RAO, CNR
    BASU, PK
    HEGDE, MS
    [J]. APPLIED SPECTROSCOPY REVIEWS, 1979, 15 (01) : 1 - 193
  • [3] UV PHOTOELECTRON-SPECTROSCOPY OF POLYSILANES AND POLYGERMANES
    SEKI, K
    YUYAMA, A
    NARIOKA, S
    ISHII, H
    HASEGAWA, S
    ISAKA, H
    FUJINO, M
    FUJIKI, M
    MATSUMOTO, N
    [J]. POLYMERIC MATERIALS FOR MICROELECTRONIC APPLICATIONS: SCIENCE AND TECHNOLOGY, 1994, 579 : 398 - 407
  • [4] IR and UV study of reversible water-induced structural transformations of poly(manganese 1,1′-ferrocenediyl-bis(H-phosphinate)) and poly(cobalt 1,1′-ferrocenediyl-bis(H-phosphinate))
    Gerasimova, Tatiana
    Shekurov, Ruslan
    Gilmanova, Leysan
    Laskin, Artem
    Katsyuba, Sergey
    Kovalenko, Valeri
    Khrizanforov, Mikhail
    Milyukov, Vasiliy
    Sinyashin, Oleg
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2018, 1166 : 237 - 242
  • [5] HYDROGEN-BONDING PATTERNS IN FERROCENE DERIVATIVES - STRUCTURES OF 1,1'-DIPHENYL-1,1'-(1,1'-FERROCENEDIYL)DIETHANOL AND 1,1'-(1,1'-FERROCENEDIYL)DIETHANOL
    GALLAGHER, JF
    FERGUSON, G
    GLIDEWELL, C
    ZAKARIA, CM
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 18 - 23
  • [6] UV PHOTOELECTRON-SPECTROSCOPY OF ORGANIC MOLECULAR MATERIALS
    INOKUCHI, H
    SEKI, K
    SATO, N
    [J]. PHYSICA SCRIPTA, 1987, T17 : 93 - 103
  • [7] UV PHOTOELECTRON-SPECTROSCOPY OF OH AND OD RADICALS
    VANLONKHUYZEN, H
    DELANGE, CA
    [J]. MOLECULAR PHYSICS, 1984, 51 (03) : 551 - 568
  • [8] APPLICATION OF PHOTOELECTRON-SPECTROSCOPY TO MOLECULAR-PROPERTIES .30. PROTOTROPY OF 1-HYDROXY-1,2,3-TRIAZOLE STUDIED BY UV PHOTOELECTRON-SPECTROSCOPY
    GUIMON, C
    KHAYAR, S
    PFISTERGUILLOUZO, G
    BEGTRUP, M
    [J]. SPECTROSCOPY LETTERS, 1987, 20 (02) : 105 - 110
  • [9] CRYSTAL-STRUCTURE OF (1,1'-FERROCENEDIYL)DIPHENYLSILANE
    STOECKLIEVANS, H
    OSBORNE, AG
    WHITELEY, RH
    [J]. HELVETICA CHIMICA ACTA, 1976, 59 (07) : 2402 - 2406
  • [10] RING-TILTED FERROCENOPHANES - THE CRYSTAL AND MOLECULAR-STRUCTURES OF "(1,1'-FERROCENEDIYL)DIPHENYLGERMANE AND "(1,1'-FERROCENEDIYL)PHENYLPHOSPHINE
    STOECKLIEVANS, H
    OSBORNE, AG
    WHITELEY, RH
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 194 (01) : 91 - 101
12345