DIELECTRIC-RELAXATION STUDIES OF HETEROGENEOUSLY SUBSTITUTED CELLULOSE-ACETATE AND ITS PLASTICIZATION BY DIBUTYL PHTHALATE

被引:3
|
作者
DOYLE, SJ [1 ]
PETHRICK, RA [1 ]
机构
[1] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,THOMAS GRAHAM BLDG,CATHEDRAL ST,GLASGOW G1 1XL,SCOTLAND
关键词
CELLULOSE ACETATE; DIBUTYL PHTHALATE; HETEROGENEOUS SUBSTITUTION; DIELECTRIC RELAXATIONS MORPHOLOGY;
D O I
10.1002/pi.4990270407
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Dielectric relaxation measurements are reported on plasticized commercial and heterogeneously substituted cellulose acetate. Differences in the observed behaviour are attributed to the retention of a degree of crystallinity and microscopic structure in the original substituted cellulose samples. A comparison of dynamic mechanical and dielectric relaxation data further emphasizes the influence of the nature of the original morphology on the micro dynamics.
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页码:321 / 331
页数:11
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