Functional Conducting Polymers via Thiol-ene Chemistry

被引：15
|
作者：
Feldman, Kathleen E. [1 ]
Martin, David C. [1 ]
机构：
[1] Univ Delaware, Dept Mat Sci & Engn, Newark, DE 19716 USA
来源：
BIOSENSORS-BASEL | 2012年 / 2卷 / 03期
基金：
美国国家科学基金会;
关键词：
conducting polymer; thiol-ene; ProDOT; functionalization;
D O I：
10.3390/bios2030305
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
We demonstrate here that thiol-ene chemistry can be used to provide side-chain functionalized monomers based on 3,4-propylenedioxythiophene ( ProDOT) containing ionic, neutral, hydrophobic, and hydrophilic side chains. All reactions gave high yields and purification could generally be accomplished through precipitation. These monomers were polymerized either chemically or electro-chemically to give soluble materials or conductive films, respectively. This strategy provides for facile tuning of the solubility, film surface chemistry, and film morphology of this class of conducting polymers.
引用
收藏
页码：305 / 317
页数：13
相关论文
共 50 条
  • [1] Cysteine-Functional Polymers via Thiol-ene Conjugation
    Kuhlmann, Matthias
    Reimann, Oliver
    Hackenberger, Christian P. R.
    Groll, Juergen
    [J]. MACROMOLECULAR RAPID COMMUNICATIONS, 2015, 36 (05) : 472 - 476
  • [2] Functional block copolymers via thiol-ene click chemistry
    Killops, Kato L.
    Gupta, Nalini
    Dimitriou, Michael D.
    Lynd, Nathaniel A.
    Jung, Hyunjung
    Bang, Joona
    Campos, Luis M.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
  • [3] Norbornenyl-Based RAFT Agents for the Preparation of Functional Polymers via Thiol-Ene Chemistry
    Stamenovic, Milan M.
    Espeel, Pieter
    Van Camp, Wim
    Du Prez, Filip E.
    [J]. MACROMOLECULES, 2011, 44 (14) : 5619 - 5630
  • [4] Functional Graphene by Thiol-ene Click Chemistry
    Nguyen Dang Luong
    Le Hoang Sinh
    Johansson, Leena-Sisko
    Campell, Joseph
    Seppala, Jukka
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (08) : 3183 - 3186
  • [5] Gelatin hydrogels via thiol-ene chemistry
    Laura Russo
    Antonella Sgambato
    Roberta Visone
    Paola Occhetta
    Matteo Moretti
    Marco Rasponi
    Francesco Nicotra
    Laura Cipolla
    [J]. Monatshefte für Chemie - Chemical Monthly, 2016, 147 : 587 - 592
  • [6] Gelatin hydrogels via thiol-ene chemistry
    Russo, Laura
    Sgambato, Antonella
    Visone, Roberta
    Occhetta, Paola
    Moretti, Matteo
    Rasponi, Marco
    Nicotra, Francesco
    Cipolla, Laura
    [J]. MONATSHEFTE FUR CHEMIE, 2016, 147 (03): : 587 - 592
  • [7] Simple and rapid functionalization of conjugated polymers via thiol-ene "click" chemistry
    Tropp, Joshua
    Amato, Douglas
    Patton, Derek
    Azoulay, Jason
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [8] Recent advances in flame retardant polymers via thiol-ene click chemistry
    Cakmakci, Emrah
    [J]. JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2023, 60 (12): : 817 - 840
  • [9] Facile and versatile platform for the preparation of functional polyethylenes via thiol-ene chemistry
    Xiao, Zeyun
    Bennett, Christopher W.
    Connal, Luke A.
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2015, 53 (17) : 1957 - 1960
  • [10] Synthesis of Functional Polymer Materials via Thiol-Ene/Yne Click Chemistry
    Yang Zhenglong
    Chen Qiuyun
    Zhou Dan
    Bu Yilong
    [J]. PROGRESS IN CHEMISTRY, 2012, 24 (2-3) : 395 - 404
12345