UNUSUAL MIXED-METAL CLUSTER REACTIONS - FORMATION OF THE MIXED-METAL CHAIN RH2RU3(CO)(10)(MU-SET)(8)

被引：1
|
作者：
JAASKELAINEN, S
PURSIAINEN, J
PAKKANEN, TA
机构：
[1] Department of Chemistry, University of Joensuu, SF-80101 Joensuu
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 487卷 / 1-2期
关键词：
RHODIUM; RUTHENIUM; CARBONYL; CLUSTERS; THIOL; CRYSTAL STRUCTURE;
D O I：
10.1016/0022-328X(94)05114-Q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The tetranuclear mixed metal carbonyl cluster HRuRh3(CO)(12) reacts with ethanethiol to give a pentanuclear compound Rh2Ru3(CO)(10)(mu-SEt)(8) as a minor product. An X-ray diffraction study has revealed that five metal atoms form a thiolate-bridged chain structure without direct metal-metal bonds. The rhodium atoms end the chain, and each metal has two terminal carbonyl ligands.
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收藏
页码：197 / 200
页数：4
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