ASYMMETRIC DOUBLE HYDROBORATION OF 1,3-DIENES CATALYZED BY CHIRAL PHOSPHINE-RHODIUM COMPLEXES

被引：53
|
作者：
MATSUMOTO, Y
HAYASHI, T
机构：
[1] HOKKAIDO UNIV,CATALYSIS RES CTR,KITA KU,SAPPORO,HOKKAIDO 060,JAPAN
[2] HOKKAIDO UNIV,GRAD SCH PHARMACEUT SCI,KITA KU,SAPPORO,HOKKAIDO 060,JAPAN
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 28期
关键词：
D O I：
10.1016/S0040-4039(00)92714-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reaction of 1-phenyl-1,3-butadiene with catecholborane in the presence of a rhodium catalyst bearing triarylphosphine ligand such as PPh3 or dppf proceeded regioselectively to give, after oxidation, anti-1-phenyl-1,3-butanediol in a good yield. Use of (R)-BINAP as a chiral ligand for the catalytic hydroboration gave optically active (1S,3R)-1-phenyl-1,3-butanediol of up to 67% ee.
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页码：3387 / 3390
页数：4
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