CHEMICAL EFFECT ON INTENSITY RATIOS OF K-SERIES X-RAYS IN VANADIUM, CHROMIUM AND MANGANESE COMPOUNDS

被引：18
|
作者：
TAMAKI, Y
机构：
[1] Department of Chemistry, Miyagi University of Education, Sendai, 980, Aoba, Aoba-ku
来源：
X-RAY SPECTROMETRY | 1995年 / 24卷 / 05期
关键词：
D O I：
10.1002/xrs.1300240504
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
K alpha and K beta x-ray fluorescence spectra of various V, Cr and Mn compounds were measured with a Bragg spectrometer. The relative intensities of the K beta(1,3), K beta(2), K beta' and K beta '' lines with respect to the K alpha line were determined to confirm the chemical effect on the K beta/K alpha intensity ratio obtained using a Si(Li) detector, Chemical effects on each component line are discussed with respect to the oxidation state of the metal ions. The relative importance of an increase in transition probabilities of the K beta(2) group (K beta(2) and K beta '') was evaluated in the determination of the overall K beta/K alpha ratio.
引用
收藏
页码：235 / 240
页数：6
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