ALKALI NIOBIUM AND TANTALUM SILICATE-GLASSES AND FERROELECTRIC GLASS-CERAMICS

被引：17
|
作者：
VERNACOTOLA, DE
机构：
来源：
RARE ELEMENTS IN GLASSES | 1994年 / 94-9卷
关键词：
D O I：
10.4028/www.scientific.net/KEM.94-95.379
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Properties and structure of alkali niobium and tantalum silicate glasses are discussed. Property/composition studies of potassium silicate based glasses indicate that niobium and tantalum act as intermediates in the glass network, by forming [MO(6)]-R(+) octahedral units (where M = Nb or Ta, and R = Li+, Na+, or K+). The crystallization behavior and unique properties of the glass-ceramic derivatives of these glasses, including their ferroelectric and electrooptical nature, are also discussed.
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页码：379 / 408
页数：30
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